Inhibitors for the hepatitis C virus RNA polymerase explored by SAR with advanced machine learning methods

Bioorg Med Chem. 2013 Jun 1;21(11):3127-37. doi: 10.1016/j.bmc.2013.03.032. Epub 2013 Mar 29.

Abstract

Hepatitis C virus (HCV) is a global health challenge, affecting approximately 200 million people worldwide. In this study we developed SAR models with advanced machine learning classifiers Random Forest and k Nearest Neighbor Simulated Annealing for 679 small molecules with measured inhibition activity for NS5B genotype 1b. The activity was expressed as a binary value (active/inactive), where actives were considered molecules with IC50 ≤0.95 μM. We applied our SAR models to various drug-like databases and identified novel chemical scaffolds for NS5B inhibitors. Subsequent in vitro antiviral assays suggested a new activity for an existing prodrug, Candesartan cilexetil, which is currently used to treat hypertension and heart failure but has not been previously tested for anti-HCV activity. We also identified NS5B inhibitors with two novel non-nucleoside chemical motifs.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, N.I.H., Intramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Antihypertensive Agents / chemistry*
  • Antiviral Agents / chemistry*
  • Artificial Intelligence
  • Benzimidazoles / chemistry*
  • Biphenyl Compounds / chemistry*
  • Databases, Chemical
  • Drug Discovery
  • Drug Repositioning
  • Hepacivirus / chemistry
  • Hepacivirus / enzymology
  • Molecular Docking Simulation
  • RNA-Dependent RNA Polymerase / antagonists & inhibitors*
  • RNA-Dependent RNA Polymerase / chemistry
  • ROC Curve
  • Structure-Activity Relationship
  • Tetrazoles / chemistry*
  • Viral Nonstructural Proteins / antagonists & inhibitors*
  • Viral Nonstructural Proteins / chemistry

Substances

  • Antihypertensive Agents
  • Antiviral Agents
  • Benzimidazoles
  • Biphenyl Compounds
  • Tetrazoles
  • Viral Nonstructural Proteins
  • NS-5 protein, hepatitis C virus
  • RNA-Dependent RNA Polymerase
  • candesartan cilexetil