In this study, we fabricated a Cr2O3 (0001) film without and with a Pt buffer layer and investigated its effect on perpendicular exchange coupling in a Cr2O3/Co3Pt interface. The results showed that the exchange bias field (μ0Hex) and blocking temperature (TB) of a Cr2O3 film without and with Pt were very different. The Cr2O3 film without Pt had a lower μ0Hex of 176 Oe and a lower TB of 75 K, whereas that with Pt had a higher μ0Hex of 436 Oe and a higher TB of 150 K. We discussed this difference in μ0Hex and TB values based on collinear/non-collinear coupling in a ferromagnetic and antiferromagnetic interface using Meiklejohn and Bean's exchange anisotropy model.