Angular dependence of the exchange interaction in fluoride-bridged Gd(III)-Cr(III) complexes

Saurabh Kumar Singh; Kasper S Pedersen; Marc Sigrist; Christian Aa Thuesen; Magnus Schau-Magnussen; Hannu Mutka; Stergios Piligkos; Høgni Weihe; Gopalan Rajaraman; Jesper Bendix

doi:10.1039/c3cc42552e

Angular dependence of the exchange interaction in fluoride-bridged Gd(III)-Cr(III) complexes

Chem Commun (Camb). 2013 Jun 21;49(49):5583-5. doi: 10.1039/c3cc42552e.

Authors

Saurabh Kumar Singh¹, Kasper S Pedersen, Marc Sigrist, Christian Aa Thuesen, Magnus Schau-Magnussen, Hannu Mutka, Stergios Piligkos, Høgni Weihe, Gopalan Rajaraman, Jesper Bendix

Affiliation

¹ Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, 400076, India.

PMID: 23677003
DOI: 10.1039/c3cc42552e

Abstract

The observed angular variation of the magnetic exchange coupling parameter in a series of fluoride-bridged chromium(III)-gadolinium(III) complexes is explained by DFT calculations.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Chromium / chemistry*
Fluorides / chemistry*
Gadolinium / chemistry*
Models, Molecular
Organometallic Compounds / chemistry*
Quantum Theory

Substances

Organometallic Compounds
Chromium
Gadolinium
Fluorides