Nanometer-nanosecond oscillatory expansion and contraction behavior of polymer films induced by 248 nm excimer laser excitation

Chemphyschem. 2000 Nov 3;1(3):137-9. doi: 10.1002/1439-7641(20001103)1:3<137::AID-CPHC137>3.0.CO;2-Y.

Abstract

Microregional mechanical measurements of a poly[methylmethacrylate) film can be made by a combined probe/measurement laser system, as represented in the picture. The localized nature of the laser systems allow quantification of the degree of expansion and contraction processes, as well as the glass-rubber transition. Such nondestructive techniques lead to the elucidation of polymer morphological dynamics.