Ras palmitoylation is necessary for N-Ras activation and signal propagation in growth factor signalling

Biochem J. 2013 Sep 1;454(2):323-32. doi: 10.1042/BJ20121799.

Abstract

Ras GTPases undergo post-translational modifications that govern their subcellular trafficking and localization. In particular, palmitoylation of the Golgi tags N-Ras and H-Ras for exocytotic transport and residency at the PM (plasma membrane). Following depalmitoylation, PM-Ras redistributes to all subcellular membranes causing an accumulation of palmitate-free Ras at endomembranes, including the Golgi and endoplasmic reticulum. Palmitoylation is unanimously regarded as a critical modification at the crossroads of Ras activity and trafficking control, but its precise relevance to native wild-type Ras function in growth factor signalling is unknown. We show in the present study by use of palmitoylation-deficient N-Ras mutants and via the analysis of palmitate content of agonist-activated GTP-loaded N-Ras that only palmitoylated N-Ras becomes activated by agonists. In line with an essential role of palmitoylation in Ras activation, dominant-negative RasS17N loses its blocking potency if rendered devoid of palmitoylation. Live-cell Ras-GTP imaging shows that N-Ras activation proceeds only at the PM, consistent with activated N-Ras-GTP being palmitoylated. Finally, palmitoylation-deficient N-Ras does not sustain EGF (epidermal growth factor) or serum-elicited mitogenic signalling, confirming that palmitoylation is essential for signal transduction by N-Ras. These findings document that N-Ras activation proceeds at the PM and suggest that depalmitoylation, by removing Ras from the PM, may contribute to the shutdown of Ras signalling.

MeSH terms

  • Amino Acid Substitution
  • Animals
  • Cell Line
  • Cell Membrane / metabolism*
  • Cells, Cultured
  • Chlorocebus aethiops
  • Down-Regulation*
  • Embryo, Mammalian / cytology
  • Enzyme Activation
  • Epidermal Growth Factor / metabolism*
  • GTP Phosphohydrolases / genetics
  • GTP Phosphohydrolases / metabolism*
  • Humans
  • Lipoylation
  • Membrane Proteins / agonists
  • Membrane Proteins / genetics
  • Membrane Proteins / metabolism*
  • Mice
  • Mice, Knockout
  • Mutant Proteins / agonists
  • Mutant Proteins / metabolism
  • Palmitic Acid / metabolism*
  • Protein Processing, Post-Translational
  • Protein Transport
  • Recombinant Proteins / agonists
  • Recombinant Proteins / metabolism
  • Signal Transduction*
  • ras Proteins / genetics
  • ras Proteins / metabolism*

Substances

  • Membrane Proteins
  • Mutant Proteins
  • Recombinant Proteins
  • Palmitic Acid
  • Epidermal Growth Factor
  • GTP Phosphohydrolases
  • NRAS protein, human
  • ras Proteins