Iridium(I)-catalyzed vinylic C-H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron

Chem Commun (Camb). 2013 Sep 4;49(68):7546-8. doi: 10.1039/c3cc44149k.

Abstract

Ir(I)-catalyzed C-H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki-Miyaura cross-coupling procedure.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Boron Compounds / chemical synthesis*
  • Boron Compounds / chemistry*
  • Carboxylic Acids / chemistry*
  • Catalysis
  • Iridium / chemistry*
  • Molecular Structure
  • Organometallic Compounds / chemistry*

Substances

  • Boron Compounds
  • Carboxylic Acids
  • Organometallic Compounds
  • Iridium