The relationships between particulate and soluble alkaline phosphatase activities and the concentration of phosphorus dissolved in the seawater of Toulon Bay (NW Mediterranean)

Mar Pollut Bull. 2013 Sep 15;74(1):413-9. doi: 10.1016/j.marpolbul.2013.06.003. Epub 2013 Jul 22.

Abstract

The activities of particulate and soluble phosphatase were analyzed monthly for 1 year in the coastal ecosystems of the NW Mediterranean Sea. The mean contribution of the particulate activity increased from 56% at an MUF-P concentration of 30 μM to 77% at 0.04 μM. This particulate activity was negatively correlated with the DIP, DOP and TDP concentrations when the activities were related to the seawater volume, chlorophyll a or the protein concentration. The TDP correlations were highly significant (p: 0.001). The DOP correlations were significant (p: 0.04) and became highly significant (p: 0.009) at low DIP concentrations (<0.13 μM). The DIP correlations were significant (p: 0.04) only at low DOP concentrations (<0.18 μM). Thus, the effects of seawater DIP and DOP were found to be linked. The soluble activity exhibited distinct phosphatase fractions with high (0.5-29.5 μM) and low (0.02-2 μM) Km values, but none exhibited significant correlations with phosphorus compounds.

Keywords: Alkaline phosphatase; DIP; DOP; Kinetics; MUF; MUF-P; Mediterranean Sea; Methyl umbelliferyl phosphate; Phosphorus; Plankton; SRP; TDP; dissolved inorganic phosphorus; dissolved organic phosphorus; methylumbelliferone; soluble reactive phosphorus; total dissolved phosphorus.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkaline Phosphatase / analysis
  • Alkaline Phosphatase / metabolism*
  • Bays / chemistry*
  • Chlorophyll / analysis
  • Chlorophyll A
  • Ecosystem
  • Environmental Monitoring
  • Mediterranean Sea
  • Phosphorus / analysis
  • Phosphorus / metabolism*
  • Seawater / chemistry*
  • Water Pollutants, Chemical / analysis
  • Water Pollutants, Chemical / metabolism*

Substances

  • Water Pollutants, Chemical
  • Chlorophyll
  • Phosphorus
  • Alkaline Phosphatase
  • Chlorophyll A