Probing the photothermally induced phase transitions in single-crystalline vanadium dioxide nanobeams

Nanotechnology. 2013 Aug 30;24(34):345701. doi: 10.1088/0957-4484/24/34/345701. Epub 2013 Jul 30.

Abstract

Using Raman spectroscopy, we demonstrated photothermally induced crystallographic phase transitions of vanadium dioxide (VO2) nanobeams clamped to and free-standing on a substrate. Compared to the temperature-dependent Raman measurements, the laser-power-dependent Raman characteristics provide substantial evidence for the photothermal origin of the phase transitions of the VO2 nanobeams. The laser power necessary to cause phase transitions in the free-standing nanobeam was approximately eight times smaller than the laser power used in the substrate-clamped nanobeam. Our study will enhance the understanding of the complex phase transitions of strongly correlated oxides and thereby provide a foundation for engineering desirable properties in novel devices.

Publication types

  • Research Support, Non-U.S. Gov't