Directly deposited quantum dot solids using a colloidally stable nanoparticle ink

Adv Mater. 2013 Oct 25;25(40):5742-9. doi: 10.1002/adma.201302147. Epub 2013 Aug 12.

Abstract

We develop a photovoltaic colloidal quantum dot ink that allows for lossless, single-step coating of large areas in a manufacturing-compatible process. Our materials strategy involves a solution-phase ligand exchange to transport compatible linkers that yield 1-thioglycerol-capped PbS quantum dots in dimethyl sulfoxide with a photoluminescence quantum yield of 24%. A proof-of-principle solar cell made from the ink exhibits 2.1% power conversion efficiency.

Keywords: PbS; colloidal quantum dots; ink; photovoltaics; scalable manufacturing; small mercaptans.