{Mo24Fe12} macrocycles: anion templation with large polyoxometalate guests

Xikui Fang; Laura Hansen; Fadi Haso; Panchao Yin; Abhishek Pandey; Larry Engelhardt; Igor Slowing; Tao Li; Tianbo Liu; Marshall Luban; David C Johnston

doi:10.1002/anie.201304887

{Mo24Fe12} macrocycles: anion templation with large polyoxometalate guests

Angew Chem Int Ed Engl. 2013 Sep 27;52(40):10500-4. doi: 10.1002/anie.201304887. Epub 2013 Aug 13.

Authors

Xikui Fang¹, Laura Hansen, Fadi Haso, Panchao Yin, Abhishek Pandey, Larry Engelhardt, Igor Slowing, Tao Li, Tianbo Liu, Marshall Luban, David C Johnston

Affiliation

¹ US DOE Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, IA 50011 (USA). [email protected].

PMID: 23943611
DOI: 10.1002/anie.201304887

Abstract

POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-templated supramolecular chemistry. The Keggin (left) and Dawson-type (right) polyoxoanions direct the assembly of giant metallomacrocycles through an array of weak hydrogen-bonding interactions. The concerted action of multiple hydrogen bonds keeps the templating guests embedded within the hosts, even in the solution state.

Keywords: anion templation; hydrogen bonds; magnetism; polyoxometalates; supramolecular chemistry.