Controlling the molecular topology of vinylogous iminium ions by logical substrate design: highly regio- and stereoselective aminocatalytic 1,6-addition to linear 2,4-dienals

Angew Chem Int Ed Engl. 2013 Oct 4;52(41):10780-3. doi: 10.1002/anie.201305870. Epub 2013 Sep 3.

Authors

Mattia Silvi¹, Indranil Chatterjee, Yiankai Liu, Paolo Melchiorre

Affiliation

¹ ICIQ-Institute of Chemical Research of Catalonia, Avenida Països Catalans 16, 43007 Tarragona (Spain) http://www.iciq.es/portal/862/default.aspx.

PMID: 24038707
DOI: 10.1002/anie.201305870

No abstract available

Keywords: cascade catalysis; chemoselectivity; conformational analysis; heterocycles; spiro compounds.