NAD⁺-carrying mesoporous silica nanoparticles can prevent oxidative stress-induced energy failures of both rodent astrocytes and PC12 cells

PLoS One. 2013 Sep 9;8(9):e74100. doi: 10.1371/journal.pone.0074100. eCollection 2013.

Abstract

Aim: To test the hypothesis that NAD(+)-carrying mesoporous silica nanoparticles (M-MSNs@NAD+) can effectively deliver NAD(+) into cells to produce cytoprotective effects.

Methods & materials: NAD(+) was incorporated into M-MSNs. Primary rat astrocyte cultures and PC12 cells were treated with H₂O₂, followed by post-treatment with M-MSNs@NAD+. After various durations of the post-treatment, intracellular NAD(+) levels, intracellular ATP levels and lactate dehydrogenase (LDH) release were determined.

Results & discussion: M-MSNs can be effectively loaded with NAD(+). The M-MSNs@NAD+ can significantly attenuate H₂O₂-induced NAD(+) and ATP decreases in both astrocyte cultures and PC12 cells. M-MSNs@NAD+ can also partially prevent the H₂O₂-induced LDH release from both astrocyte cultures and PC12 cells. In contrast, the NAD(+) that is spontaneously released from the M-MSNs@NAD+ is insufficient to prevent the H₂O₂-induced damage.

Conclusions: Our study has suggested the first approach that can effectively deliver NAD(+) into cells, which provides an important basis both for elucidating the roles of intracellular NAD(+) in biological functions and for therapeutic applications of NAD(+). Our study has also provided the first direct evidence demonstrating a key role of NAD(+) depletion in oxidative stress-induced ATP decreases.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adenosine Triphosphate / metabolism
  • Animals
  • Astrocytes / drug effects
  • Astrocytes / metabolism*
  • Cell Death
  • Energy Metabolism / drug effects
  • Enzyme Activation
  • Hydrogen Peroxide / pharmacology
  • L-Lactate Dehydrogenase / metabolism
  • Magnetite Nanoparticles / administration & dosage
  • Magnetite Nanoparticles / chemistry*
  • Magnetite Nanoparticles / ultrastructure
  • NAD / chemistry*
  • NAD / metabolism
  • Oxidative Stress*
  • PC12 Cells
  • Poly(ADP-ribose) Polymerases / metabolism
  • Porosity
  • Rats
  • Silicon Dioxide / chemistry*

Substances

  • Magnetite Nanoparticles
  • NAD
  • Silicon Dioxide
  • Adenosine Triphosphate
  • Hydrogen Peroxide
  • L-Lactate Dehydrogenase
  • Poly(ADP-ribose) Polymerases

Grants and funding

This study was supported by a Key Shanghai Jiao Tong University Grant for Interdisciplinary Research on Engineering and Physical Sciences (to H.G. and W.Y.), Shanghai Engineering Center Grant #11DZ2211000 (to H.G. and W.Y.), a National Key Basic Research ‘973 Program’ Grant #2010CB834306 (to W.Y.), and Chinese National Science Foundation Grant #81171098 (to W.Y.). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.