A missing link in the transformation from asymmetric to symmetric metallofullerene cages implies a top-down fullerene formation mechanism

Nat Chem. 2013 Oct;5(10):880-5. doi: 10.1038/nchem.1748. Epub 2013 Sep 15.

Abstract

Although fullerenes were discovered nearly three decades ago, the mechanism of their formation remains a mystery. Many versions of the classic 'bottom-up' formation mechanism have been advanced, starting with C2 units that build up to form chains and rings of carbon atoms and ultimately form those well-known isolated fullerenes (for example, I(h)-C60). In recent years, evidence from laboratory and interstellar observations has emerged to suggest a 'top-down' mechanism, whereby small isolated fullerenes are formed via shrinkage of giant fullerenes generated from graphene sheets. Here, we present molecular structural evidence for this top-down mechanism based on metal carbide metallofullerenes M2C2@C1(51383)-C84 (M = Y, Gd). We propose that the unique asymmetric C1(51383)-C84 cage with destabilizing fused pentagons is a preserved 'missing link' in the top-down mechanism, and in well-established rearrangement steps can form many well-known, high-symmetry fullerene structures that account for the majority of solvent-extractable metallofullerenes.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Fullerenes / chemistry*
  • Gadolinium / chemistry*
  • Magnetic Resonance Spectroscopy
  • Molecular Structure
  • Solvents / chemistry
  • Yttrium / chemistry*

Substances

  • Fullerenes
  • Solvents
  • Yttrium
  • Gadolinium