Single-molecule chemical reactions tracked at the atomic-bond level

Angew Chem Int Ed Engl. 2013 Dec 16;52(51):13521-3. doi: 10.1002/anie.201305041. Epub 2013 Oct 23.

Abstract

On the right track: Recent advances in noncontact atomic force microscopy (nc-AFM) have enabled the bond-resolved imaging of reaction pathways. In particular, unprecedented insights into complex enediyne cyclization cascades on silver surfaces were gained by single-molecule imaging.

Keywords: atomic force microscopy; molecular imaging; reaction mechanisms; scanning tunneling microscopy; surface chemistry.