Selective trioxolane based bifunctional molecular linkers for covalent heme surface functionalisation

M McConville; D F Bradley; K Zhou; D J Schiffrin; I A O'Neil

doi:10.1039/c3cc46041j

Selective trioxolane based bifunctional molecular linkers for covalent heme surface functionalisation

Chem Commun (Camb). 2014 Jan 7;50(2):186-8. doi: 10.1039/c3cc46041j.

Authors

M McConville¹, D F Bradley, K Zhou, D J Schiffrin, I A O'Neil

Affiliation

¹ Department of Chemistry University of Liverpool, Liverpool, UK. [email protected].

PMID: 24217350
DOI: 10.1039/c3cc46041j

Abstract

A bifunctional molecular linker containing both aryl diazonium and trioxolane groups was synthesised and its ability to sequentially functionalise glassy carbon and covalently immobilise heme investigated. Functionalisation was demonstrated by electrochemical techniques.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Carbon / chemistry*
Diazonium Compounds / chemistry*
Electrochemical Techniques
Heme / chemistry*
Heterocyclic Compounds, 1-Ring / chemistry*
Surface Properties

Substances

Diazonium Compounds
Heterocyclic Compounds, 1-Ring
Heme
Carbon