Adjuvant activity of CpG-ODN formulated as a liquid crystal

Biomaterials. 2014 Mar;35(8):2529-42. doi: 10.1016/j.biomaterials.2013.12.002. Epub 2013 Dec 30.

Abstract

The adjuvants approved in human vaccine with recombinant/purified antigens induce weak cellular immune response and so the development of new adjuvant strategies is critical. CpG-ODN has successfully been used as an adjuvant (phase I-III clinical trials) but its bioavailability needs to be improved. We investigated the adjuvant ability of CpG-ODN formulated with a liquid crystal nanostructure of 6-O-ascorbyl palmitate (Coa-ASC16). Mice immunized with OVA/CpG-ODN/Coa-ASC16 elicited a potent specific IgG1, IgG2a, Th1 and Th17 cellular response without systemic adverse effects. These responses were superior to those induced by OVA/CpG-ODN (solution of OVA with CpG-ODN) and to those induced by the formulation OVA/CpG-ODN/Al(OH)3. Immunization with OVA/CpG-ODN/Coa-ASC16 resulted in a long-lasting cell-mediated immune response (at least 6.5 months). Furthermore, Coa-ASC16 alone allows a controlled release of CpG-ODN in vitro and induces local inflammatory response, independent of TLR4 signaling, characterized by an influx of neutrophils and Ly6C(high) monocytes and pro-inflammatory cytokines. Remarkably, the adjuvant capacity of CpG-ODN co-injected with Coa-ASC16 (OVA/CpG-ODN plus Coa-ASC16) was similar to the adjuvant activity of OVA/CpG-ODN, supporting the requirement for whole formulation to help CpG-ODN adjuvanticity. These results show the potential of this formulation, opening a new avenue for the development of better vaccines.

Keywords: Adjuvant; Ascorbyl palmitate; CpG-ODN; Liquid crystal; Vaccine.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adjuvants, Immunologic / chemistry
  • Adjuvants, Immunologic / pharmacokinetics*
  • Alanine Transaminase / blood
  • Animals
  • Antigens / immunology
  • Ascorbic Acid / analogs & derivatives
  • Ascorbic Acid / chemistry
  • Ascorbic Acid / pharmacokinetics
  • Aspartate Aminotransferases / blood
  • Biological Availability
  • Cells, Cultured
  • Female
  • Immunity, Cellular*
  • Immunization
  • Immunoglobulin G / immunology
  • Liquid Crystals / chemistry*
  • Mice
  • Mice, Inbred BALB C
  • Mice, Inbred C57BL
  • Nanostructures / chemistry
  • Oligodeoxyribonucleotides / chemistry
  • Oligodeoxyribonucleotides / pharmacokinetics*
  • Ovalbumin / immunology
  • Signal Transduction
  • Spleen / cytology
  • Spleen / metabolism
  • Toll-Like Receptor 4 / genetics
  • Toll-Like Receptor 4 / metabolism
  • Vaccines / chemistry
  • Vaccines / immunology

Substances

  • Adjuvants, Immunologic
  • Antigens
  • CPG-oligonucleotide
  • Immunoglobulin G
  • Oligodeoxyribonucleotides
  • Tlr4 protein, mouse
  • Toll-Like Receptor 4
  • Vaccines
  • Ovalbumin
  • Aspartate Aminotransferases
  • Alanine Transaminase
  • Ascorbic Acid
  • 6-O-palmitoylascorbic acid