The synthesis and structure of chiral enamine N-oxides

Chem Commun (Camb). 2014 Jul 14;50(55):7336-9. doi: 10.1039/c3cc47928e.

Abstract

Chiral enamine N-oxides have been synthesised by a diastereoselective intermolecular reverse-Cope cycloaddition reaction between chiral hydroxylamines and activated acetylenes. Their structures have been investigated by NMR, X-ray crystallography and computational methods.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Cycloaddition Reaction
  • Magnetic Resonance Spectroscopy
  • Models, Molecular
  • Oxides / chemical synthesis
  • Oxides / chemistry*
  • Stereoisomerism

Substances

  • Oxides