Remote trap passivation in colloidal quantum dot bulk nano-heterojunctions and its effect in solution-processed solar cells

Adv Mater. 2014 Jul 16;26(27):4741-7. doi: 10.1002/adma.201400297. Epub 2014 Jun 4.

Abstract

More-efficient charge collection and suppressed trap recombination in colloidal quantum dot (CQD) solar cells is achieved by means of a bulk nano-heterojunction (BNH) structure, in which p-type and n-type materials are blended on the nanometer scale. The improved performance of the BNH devices, compared with that of bilayer devices, is displayed in higher photocurrents and higher open-circuit voltages (resulting from a trap passivation mechanism).

Keywords: bulk nano-heterojunctions; colloidal quantum dots; recombination; solar cells; trap states.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Colloids
  • Electric Power Supplies*
  • Lead / chemistry
  • Nanotechnology / instrumentation*
  • Quantum Dots / chemistry*
  • Solar Energy*
  • Solutions
  • Sulfides / chemistry
  • Temperature
  • Zinc Oxide / chemistry

Substances

  • Colloids
  • Solutions
  • Sulfides
  • lead sulfide
  • Lead
  • Zinc Oxide