Nanosizing of valsartan by high pressure homogenization to produce dissolution enhanced nanosuspension: pharmacokinetics and pharmacodyanamic study

Drug Deliv. 2016;23(3):940-50. doi: 10.3109/10717544.2014.923066. Epub 2014 Jun 17.

Abstract

Purpose: The purpose of the present study was to formulate and evaluate nanosuspension of Valsartan (VAL), a poorly water soluble and low bioavailable drug (solubility of 0.18 mg mL(-1); 23% of oral bioavailability) with the aim of improving the aqueous solubility thus the bioavailability and consequently better anti-hypertensive activity.

Methods: Valsartan nanosuspension (VAL-NS) was prepared using high-pressure homogenization followed by lyophilisation. The screening of homogenization factors influencing nanosuspension was done by 3-factorial, 3-level Box-Behnken statistical design. Model suggested the influential role of homogenization pressure and cycles on drug nanosizing. The optimized formulation containing Poloxamer(-1)88 (PXM 188) was homogenized for 2 cycles at 500 and 1000 bar, followed by 5 cycles at 1500 bars.

Results: The size analysis and transmission electron microscopy showed nanometric size range and uniform shape of the nanosuspension. The in vitro dissolution showed an enhanced release of VAL from nanosuspension (VAL-NS) compared to physical mixture with PXM 188. Pharmacodynamic results showed that, oral administration of VAL-NS significantly lowered (p ≤ 0.001) blood pressure in comparison to non-homogenized VAL (VAL-Susp) in Wistar rat. The level of VAL in rat plasma treated with VAL-NS showed significant difference (p ≤ 0.005) in Cmax (1627.47 ± 112.05 ng mL(-1)), Tmax (2.00 h) and AUC0→24 (13279.2 ± 589.426 ng h mL(-1)) compared to VAL-Susp that was found to be 1384.73 ± 98.76 ng mL(-1), 3.00 h and 9416.24 ± 218.48 ng h mL(-1) respectively. The lower Tmax value, proved the enhanced dissolution rate of VAL.

Conclusion: The overall results proved that newly developed VAL-NS increased the plasma bioavailability and pharmacodyanamic potential over the reference formulation containing crude VAL.

Keywords: Anti-hypertensive; high-pressure homogenizer; nanosizing; particle size distribution; scanning electron microscopy; valsartan.

MeSH terms

  • Administration, Oral
  • Animals
  • Antihypertensive Agents / chemistry
  • Antihypertensive Agents / pharmacokinetics
  • Antihypertensive Agents / pharmacology
  • Biological Availability
  • Chemistry, Pharmaceutical / methods
  • Drug Compounding / methods
  • Excipients / chemistry
  • Freeze Drying / methods
  • Microscopy, Electron, Transmission / methods
  • Nanoparticles / chemistry*
  • Particle Size
  • Poloxamer / chemistry
  • Pressure
  • Rats
  • Rats, Wistar
  • Solubility
  • Suspensions / chemistry*
  • Suspensions / pharmacokinetics*
  • Suspensions / pharmacology
  • Valsartan / chemistry*
  • Valsartan / pharmacokinetics*
  • Valsartan / pharmacology
  • Water / chemistry

Substances

  • Antihypertensive Agents
  • Excipients
  • Suspensions
  • Water
  • Poloxamer
  • Valsartan