Synthetic molecules that protect cells from anoikis and their use in cell transplantation

Angew Chem Int Ed Engl. 2014 Oct 13;53(42):11208-13. doi: 10.1002/anie.201405829. Epub 2014 Sep 4.

Abstract

One of the major problems encountered in cell transplantation is the low level of survival of transplanted cells due to detachment-induced apoptosis, called anoikis. The present study reports on the chemical synthesis and biological evaluation of water-soluble molecules that protect suspended cells from anoikis. The synthetic molecules bind to and induce clusters of integrins and heparan-sulfate-bound syndecans, two classes of receptors that are important for extracellular matrix-mediated cell survival. Molecular biological analysis indicates that such molecules prolong the survival of suspended NIH3T3 cells, at least in part, by promoting clustering of syndecan-4 and integrin β1 on the cell surface, leading to the activation of small GTPase Rac-1 and Akt. In vivo experiments using animal disease models demonstrated the ability of the molecules to improve cell engraftment. The cluster-inducing molecules may provide a starting point for the design of new synthetic tools for cell-based therapy.

Keywords: adhesamine; anoikis; cell engraftment; peptides; self-assembly.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Anoikis / drug effects*
  • Cell Adhesion / drug effects
  • Cell Survival / drug effects
  • Cell Transplantation* / methods
  • Cells, Cultured
  • Integrin beta1 / metabolism
  • Mice
  • NIH 3T3 Cells
  • Peptides / chemistry*
  • Peptides / pharmacology*
  • Protective Agents / chemistry*
  • Protective Agents / pharmacology*
  • Rabbits
  • Syndecan-4 / metabolism

Substances

  • Integrin beta1
  • Peptides
  • Protective Agents
  • Syndecan-4