Spin-lock MR enhances the detection sensitivity of superparamagnetic iron oxide particles

Magn Reson Med. 2015 Dec;74(6):1740-9. doi: 10.1002/mrm.25544. Epub 2014 Dec 2.

Abstract

Purpose: To evaluate spin-lock MR for detecting superparamagnetic iron oxides and compare the detection sensitivity of quantitative T1ρ with T2 imaging.

Methods: In vitro experiments were performed to investigate the influence of iron oxide particle size and composition on T1ρ . These comprise T1ρ and T2 measurements (B0 = 1.41T) of agar (2%) with concentration ranges of three different iron oxide nanoparticles (IONs) (Sinerem, Resovist, and ION-Micelle) and microparticles of iron oxide (MPIO). T1ρ dispersion was measured for a range of spin-lock amplitudes (γB1 = 6.5-91 kHz). Under relevant in vivo conditions (B0 = 9.4T; γB1 = 100-1500 Hz), T1ρ and T2 mapping of the liver was performed in seven mice pre- and 24 h postinjection of Sinerem.

Results: Addition of iron oxide nanoparticles decreased T1ρ as well as the native T1ρ dispersion of agar, leading to increased contrast at high spin-lock amplitudes. Changes of T1ρ were highly linear with iron concentration and much larger than T2 changes. MPIO did not show this effect. In vivo, a decrease of T1ρ was observed with no clear influence on T1ρ dispersion.

Conclusion: By suppression of T1ρ dispersion, iron oxide nanoparticles cause enhanced T1ρ contrast compared to T2 . The underlying mechanism appears to be loss of lock. Spin-lock MR is therefore a promising technique for sensitive detection of iron oxide contrast agents.

Keywords: Spin-lock MR; T1ρ contrast agent; T1ρ dispersion; iron oxide nanoparticles; rotating frame relaxation; superparamagnetic iron oxide particles.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Contrast Media / analysis
  • Contrast Media / chemistry
  • Dextrans / analysis*
  • Dextrans / chemistry
  • Dextrans / ultrastructure*
  • Imaging, Three-Dimensional / methods*
  • Magnetic Resonance Imaging / methods*
  • Magnetic Resonance Spectroscopy / methods*
  • Magnetite Nanoparticles / analysis*
  • Magnetite Nanoparticles / chemistry
  • Magnetite Nanoparticles / ultrastructure*
  • Materials Testing
  • Molecular Imaging / methods*
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Spin Labels

Substances

  • Contrast Media
  • Dextrans
  • Magnetite Nanoparticles
  • Spin Labels
  • ferumoxtran-10