Surface modification of titanium with hydroxyapatite-heparin-BMP-2 enhances the efficacy of bone formation and osseointegration in vitro and in vivo

J Tissue Eng Regen Med. 2015 Sep;9(9):1067-77. doi: 10.1002/term.1973. Epub 2014 Dec 19.

Abstract

Surface-modified titanium (Ti) samples with hydroxyapatite (HAp) and heparin (Hep)-bone morphogenetic protein-2 (BMP-2) complex (Ti/HAp/Hep/BMP-2) were prepared, and their efficacies on the enhancements of bone formation and osseointegration in vitro and in vivo were examined as compared to Ti/HAp and Ti/Hep/BMP-2. The modified surfaces were characterized by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and contact angle goniometry. In vitro studies revealed that MG-63 human osteosarcoma cell lines grown on Ti/HAp/Hep/BMP-2 increased the amounts of alkaline phosphatase (ALP) activity, calcium deposition and the levels of OCN mRNA gene expression as compared to those grown on Ti/HAp, Ti/Hep/BMP-2 or pristine Ti. Moreover, Ti/HAp/Hep/BMP-2 exhibited higher bone volume (BV), bone volume/tissue volume (BV/TV), removal torque value and bone-implant contact (BIC) than Ti/HAp, Ti/Hep/BMP-2 or pristine Ti in vivo. Histological evaluations showed that many desirable features of bone remodelling existed at the interface between Ti/HAp/Hep/BMP-2 and the host bone. Consequently, Ti/HAp/Hep/BMP-2 may have potential for clinical use as dental or orthopaedic implants.

Keywords: bone formation; bone morphogenetic protein-2; hydroxyapatite; in vitro; in vivo; osseointegration; surface-modified titanium.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkaline Phosphatase / metabolism
  • Animals
  • Bone Development*
  • Bone Morphogenetic Protein 2 / chemistry*
  • Bone Morphogenetic Protein 2 / metabolism
  • Cell Line, Tumor
  • Durapatite / chemistry*
  • Heparin / chemistry*
  • Humans
  • In Vitro Techniques
  • Microscopy, Electron, Scanning
  • Osseointegration*
  • Osteocalcin / genetics
  • Photoelectron Spectroscopy
  • RNA, Messenger / genetics
  • Rabbits
  • Surface Properties
  • Titanium / chemistry*

Substances

  • BMP2 protein, human
  • Bone Morphogenetic Protein 2
  • RNA, Messenger
  • Osteocalcin
  • Heparin
  • Durapatite
  • Titanium
  • Alkaline Phosphatase