Crystal structure of S-hexyl (E)-3-(4-methoxy-benzyl-idene)di-thio-carbazate

M S Begum; M B H Howlader; R Miyatake; E Zangrando; M C Sheikh

doi:10.1107/S2056989015003199

Crystal structure of S-hexyl (E)-3-(4-methoxy-benzyl-idene)di-thio-carbazate

Acta Crystallogr E Crystallogr Commun. 2015 Feb 25;71(Pt 3):o199. doi: 10.1107/S2056989015003199. eCollection 2015 Mar 1.

Authors

M S Begum¹, M B H Howlader¹, R Miyatake², E Zangrando³, M C Sheikh⁴

Affiliations

¹ Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.
² Center for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan.
³ Department of Chemical and Pharmaceutical Sciences, Via Giorgieri 1, 34127 Trieste, Italy.
⁴ Department of Applied Chemistry, Faculty of Engineering, University of Toyama, 3190 Gofuku, Toyama, 930-8555, Japan.

Abstract

In the title compound, C15H22N2OS2, the di-thio-carbazate group adopts an EE conformation with respect to the C=N bond of the benzyl-idene moiety. The hexyl side chain adopts an extended conformation and the C-S-C-C torsion angle is -93.36 (13)°. In the crystal, inversion dimers linked by pairs of N-H⋯S hydrogen bonds generate R 2 (2)(8) loops.

Keywords: S-containing Schiff bases; crystal structure; dithiocarbazate; hydrogen bonding.