Crystal structure of bis-[S-hexyl 3-(4-methyl-benzyl-idene)di-thio-carbazato-κ(2) N (3),S]nickel(II)

M B H Howlader; M S Begum; M C Sheikh; R Miyatake; E Zangrando

doi:10.1107/S2056989015000328

Crystal structure of bis-[S-hexyl 3-(4-methyl-benzyl-idene)di-thio-carbazato-κ(2) N (3),S]nickel(II)

Acta Crystallogr E Crystallogr Commun. 2015 Jan 14;71(Pt 2):m26-7. doi: 10.1107/S2056989015000328. eCollection 2015 Feb 1.

Authors

M B H Howlader¹, M S Begum¹, M C Sheikh², R Miyatake³, E Zangrando⁴

Affiliations

¹ Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.
² Department of Applied Chemistry, Faculty of Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan.
³ Center for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan.
⁴ Department of Chemical and Pharmaceutical Sciences, via Giorgieri 1, 34127 Trieste, Italy.

Abstract

In the title complex, [Ni(C15H21N2S2)2], the Ni(II) atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands. In the crystal, the complex mol-ecules stack at a distance of 4.6738 (3) Å along the a axis, which exclude any significant inter-actions between the aromatic rings.

Keywords: crystal structure; dithiocarbazate; nickel complex.