Crystal structure of S-hexyl (E)-3-(4-methyl-benzyl-idene)di-thio-carbazate

M B H Howlader; M S Begum; M C Sheikh; R Miyatake; E Zangrando

doi:10.1107/S2056989015000080

Crystal structure of S-hexyl (E)-3-(4-methyl-benzyl-idene)di-thio-carbazate

Acta Crystallogr E Crystallogr Commun. 2015 Jan 10;71(Pt 2):o103-4. doi: 10.1107/S2056989015000080. eCollection 2015 Feb 1.

Authors

M B H Howlader¹, M S Begum¹, M C Sheikh², R Miyatake³, E Zangrando⁴

Affiliations

¹ Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.
² Department of Applied Chemistry, Faculty of Engineering, University of Toyama, 3190 Gofuku, Toyama, 930-8555, Japan.
³ Center for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama, 930-8555, Japan.
⁴ Department of Chemical and Pharmaceutical Sciences, via Giorgieri 1, 34127, Trieste, Italy.

Abstract

In the title compound, C15H22N2S2, the di-thio-carbazate group adopts an E conformation with respect to the C=N bond of the benzyl-idene moiety. In the crystal, mol-ecules are linked by pairs of N-H⋯S hydrogen bonds, forming inversion dimers with an R (2) 2(8) ring motif. The dimers are linked via C-H⋯π inter-actions, forming chains propagating along [100].

Keywords: C—H⋯π interactions.; N—H⋯S hydrogen bonds; S-hexyl dithiocarbazate; bidentate Schiff base; crystal structure.