Abstract
A TBHP-mediated palladium-catalyzed tandem isomerization-Wacker oxidation of terminal alkenes was developed. This methodology provides a new efficient and simple route for conversion of a range of allyl arenes directly into aryl ethylketones in good yields with high chemoselectivity.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemistry*
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Allyl Compounds / chemistry*
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Catalysis
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Ketones / chemistry*
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Molecular Structure
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Oxidation-Reduction
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Palladium / chemistry*
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Stereoisomerism
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tert-Butylhydroperoxide / chemistry*
Substances
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Alkenes
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Allyl Compounds
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Ketones
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Palladium
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tert-Butylhydroperoxide