Biodegradable chitosan and polylactic acid-based intraocular micro-implant for sustained release of methotrexate into vitreous: analysis of pharmacokinetics and toxicity in rabbit eyes

Graefes Arch Clin Exp Ophthalmol. 2015 Aug;253(8):1297-305. doi: 10.1007/s00417-015-3007-1. Epub 2015 Apr 21.

Abstract

Purpose: The purpose of this study was to evaluate the pharmacokinetics and toxicity of a chitosan (CS) and polylactic acid (PLA) based methotrexate (MTX) intravitreal micro-implant in an animal model using rabbit eyes.

Methods: CS- and PLA-based micro-implants containing 400 μg of MTX were fabricated using lyophilization and dip-coating techniques. The micro-implants were surgically implanted in the vitreous of eight New Zealand rabbits employing minimally invasive technique. The PLA-coated CS-MTX micro-implant was inserted in the right eye and the placebo micro-implant in the left eye of each rabbit. Two rabbits were euthanized at each pre-determined time point post-implantation (days 5, 12, 19, and 33) for pharmacokinetics and histopathology evaluation.

Results: A therapeutic concentration of MTX (0.1-1.0 μM) in the vitreous was detected in the rabbit eyes studied for 33 days. The MTX release from the coated micro-implants followed a first order kinetics (R (2) ~ 0.88), implying that MTX release depends on the concentration of MTX in the micro-implant. Histopathological analysis of the enucleated eyes failed to show any signs of infection or tissue toxicity in any of the specimens.

Conclusion: The PLA-coated CS-MTX micro-implants were able to deliver therapeutic release of MTX for a period of more than 1 month without detectable toxicity in a rabbit model. The micro-implants can be further investigated as a prospective alternative to current treatment protocols of repeated intravitreal MTX injections in intraocular disorders such as primary intraocular lymphoma, and selected cases of non-microbial intraocular inflammation.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Absorbable Implants*
  • Animals
  • Antimetabolites, Antineoplastic / pharmacokinetics*
  • Antimetabolites, Antineoplastic / toxicity
  • Biocompatible Materials
  • Chitosan / pharmacokinetics*
  • Chitosan / toxicity
  • Drug Delivery Systems*
  • Drug Implants
  • Intravitreal Injections
  • Lactic Acid / pharmacokinetics*
  • Lactic Acid / toxicity
  • Methotrexate / pharmacokinetics*
  • Methotrexate / toxicity
  • Models, Animal
  • Polyesters
  • Polymers / pharmacokinetics*
  • Polymers / toxicity
  • Rabbits
  • Retina / drug effects
  • Vitreous Body / metabolism*

Substances

  • Antimetabolites, Antineoplastic
  • Biocompatible Materials
  • Drug Implants
  • Polyesters
  • Polymers
  • Lactic Acid
  • poly(lactide)
  • Chitosan
  • Methotrexate