ThPt2: A New Representative of Close Packed Tetragonal Structures

Inorg Chem. 2015 Jul 6;54(13):6338-46. doi: 10.1021/acs.inorgchem.5b00669. Epub 2015 Jun 23.

Abstract

ThPt2 crystallizes with unique type of structure (space group I4/mmm, a = 4.1565(1) Å, c = 14.3663(7) Å, Pearson symbol tI12), which belongs to the group of the close packed tetragonal structures. An analysis of the chemical bonding by the electron localizability approach reveals the formation of two-dimensional layered platinum anionic substructures interlinked by strongly polar bonds to Th. Measurements of magnetic susceptibility, electrical resistivity, and specific heat show ThPt2 to be diamagnetic with metallic type of electrical conductivity in good agreement with the calculated electronic structure (N(EF) = 0.9 states eV(-1) f.u.(-1)).