Two Ene-Yne Metathesis Approaches to the Total Synthesis of Amphidinolide P

Org Lett. 2015 Jul 17;17(14):3510-3. doi: 10.1021/acs.orglett.5b01601. Epub 2015 Jun 26.

Abstract

The total synthesis of amphidinolide P was achieved through two different ene-yne metathesis approaches. In each approach, the metathesis step was performed at late stages in the synthesis with all other functionality present. By forging two successful pathways to the synthesis of 1, some of the strengths and weaknesses of metathesis-intensive synthetic strategies were identified.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkynes / chemistry*
  • Cyclization
  • Cycloparaffins / chemistry*
  • Macrolides / chemical synthesis*
  • Macrolides / chemistry
  • Molecular Structure

Substances

  • Alkynes
  • Cycloparaffins
  • Macrolides
  • amphidinolide P