Raman and infrared spectroscopy study on structure and microstructure of glass-ceramic materials from SiO2-Al2O3-Na2O-K2O-CaO system modified by variable molar ratio of SiO2/Al2O3

Janusz Partyka; Magdalena Leśniak

doi:10.1016/j.saa.2015.07.045

Raman and infrared spectroscopy study on structure and microstructure of glass-ceramic materials from SiO2-Al2O3-Na2O-K2O-CaO system modified by variable molar ratio of SiO2/Al2O3

Spectrochim Acta A Mol Biomol Spectrosc. 2016 Jan 5:152:82-91. doi: 10.1016/j.saa.2015.07.045. Epub 2015 Jul 8.

Authors

Janusz Partyka¹, Magdalena Leśniak²

Affiliations

¹ AGH University of Science and Technology, Faculty of Materials Science and Ceramics, Department of Ceramics and Refractories, Poland. Electronic address: [email protected].
² AGH University of Science and Technology, Faculty of Materials Science and Ceramics, Department of Silicate Chemistry and Macromolecular Compounds, Poland.

PMID: 26196934
DOI: 10.1016/j.saa.2015.07.045

Abstract

This paper is focused on the effect of the molar ratio of SiO2/Al2O3 on the microstructure and structure of the internal aluminium-silicon-oxide lattice of the glass-ceramic materials from the SiO2-Al2O3-Na2O-K2O-CaO system. In order to examine the real composition of the obtained samples, a chemical analysis was performed. Following the heat-treatment procedure, pseudowollastonite, anorthite and the vitreous phase were identified. In order to determine the microstructure, research using the scanning electron microscope (SEM) with EDS was done. For the inner structural study, X-ray diffraction (XRD), Raman spectroscopy as well as MIR and FIR spectroscopy were performed.

Keywords: Glass lattice; Glass–ceramic; Microstructure; Molar ratio; Structure.

Publication types

Research Support, Non-U.S. Gov't