The aim of this study was to investigate the bond strength of dental porcelain and the preheated Zr-14Nb alloy, and compare this strength with that of titanium. White oxide layers, which were predominantly composed of monoclinic zirconia, were formed on the preheated sample groups, and exhibited a greater roughness than the control samples. At the metal-ceramic interface, a greater Nb diffusion range was observed than in the control samples. The bond strengths of the samples subjected to 20min preheating treatment were the lowest (33.6 ± 3.2 MPa), which may be ascribed to the formation of a brittle thick oxide layer under excessive heat treatment. The samples subjected to this heat treatment for 5 min exhibited the highest mean bond strength (43.7 ± 5.9 MPa), which was significantly higher than that of titanium (35.3 ± 3.5 MPa). Thus, the Zr-14Nb alloy is a promising candidate for fixed dental prosthesis, as long as the appropriate treatment conditions are adopted.
Keywords: Dental porcelain; Fixed dental prostheses; Preheating treatment; Shear bond strength; Zr–Nb alloy.
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