Nizwaside: a new anticancer pregnane glycoside from the sap of Desmidorchis flava

Arch Pharm Res. 2015 Dec;38(12):2137-42. doi: 10.1007/s12272-015-0653-0. Epub 2015 Sep 3.

Abstract

The sap from the succulent Desmidorchis flava (N.E.Br) Meve and Liede yielded a new pregnane glycoside, named nizwaside whose structure was established using 1D and 2D NMR techniques as well as mass spectrometry (ESIMS). Nizwaside was tested for anticancer, DPPH antioxidant, urease enzyme inhibition, α-glucosidase enzyme inhibition and acetylcholinesterase inhibition activities. Interestingly, nizwaside showed significant anti-proliferative effects on MDA MB231 breast cancer cells with an IC(50) of 23.5 µg/ml. Moreover, nizwaside was more effective than Doxorubicin, a well-known clinical anticancer drug, in suppressing MDA MB231 cell proliferation even at concentrations lower than that of Doxorubicin (75 µg/ml nizwaside vs. 100 µg/ml Doxorubicin). On the other hand, nizwaside showed relatively weak antioxidant activity with 15 % inhibition.

Keywords: Anticancer activity; Asclepiadaceae; Desmidorchis flava; NMR; Natural product; Pregnane glycoside.

MeSH terms

  • Antineoplastic Agents, Phytogenic / chemistry*
  • Antineoplastic Agents, Phytogenic / isolation & purification*
  • Antineoplastic Agents, Phytogenic / pharmacology
  • Apocynaceae*
  • Cell Line, Tumor
  • Cell Survival / drug effects
  • Cell Survival / physiology
  • Dose-Response Relationship, Drug
  • Female
  • Glycosides / chemistry*
  • Glycosides / isolation & purification*
  • Glycosides / pharmacology
  • Humans
  • Plant Extracts / chemistry
  • Plant Extracts / isolation & purification
  • Plant Extracts / pharmacology
  • Pregnanes / chemistry*
  • Pregnanes / isolation & purification*
  • Pregnanes / pharmacology

Substances

  • Antineoplastic Agents, Phytogenic
  • Glycosides
  • Plant Extracts
  • Pregnanes
  • nizwaside
  • pregnane glycoside