FR171456 is a specific inhibitor of mammalian NSDHL and yeast Erg26p

Nat Commun. 2015 Oct 12:6:8613. doi: 10.1038/ncomms9613.

Abstract

FR171456 is a natural product with cholesterol-lowering properties in animal models, but its molecular target is unknown, which hinders further drug development. Here we show that FR171456 specifically targets the sterol-4-alpha-carboxylate-3-dehydrogenase (Saccharomyces cerevisiae--Erg26p, Homo sapiens--NSDHL (NAD(P) dependent steroid dehydrogenase-like)), an essential enzyme in the ergosterol/cholesterol biosynthesis pathway. FR171456 significantly alters the levels of cholesterol pathway intermediates in human and yeast cells. Genome-wide yeast haploinsufficiency profiling experiments highlight the erg26/ERG26 strain, and multiple mutations in ERG26 confer resistance to FR171456 in growth and enzyme assays. Some of these ERG26 mutations likely alter Erg26 binding to FR171456, based on a model of Erg26. Finally, we show that FR171456 inhibits an artificial Hepatitis C viral replicon, and has broad antifungal activity, suggesting potential additional utility as an anti-infective. The discovery of the target and binding site of FR171456 within the target will aid further development of this compound.

MeSH terms

  • 3-Hydroxysteroid Dehydrogenases / antagonists & inhibitors*
  • 3-Hydroxysteroid Dehydrogenases / genetics
  • Antifungal Agents / chemistry*
  • Candida albicans
  • Cholesterol / analogs & derivatives*
  • Cholesterol / chemistry
  • Drug Resistance, Fungal / genetics
  • Ergosterol / biosynthesis
  • Mutation
  • Saccharomyces cerevisiae / genetics*
  • Saccharomyces cerevisiae Proteins / antagonists & inhibitors*
  • Saccharomyces cerevisiae Proteins / genetics

Substances

  • Antifungal Agents
  • FR171456
  • Saccharomyces cerevisiae Proteins
  • Cholesterol
  • 3-Hydroxysteroid Dehydrogenases
  • ERG26 protein, S cerevisiae
  • Ergosterol