Planar Dy3 + Dy3 clusters: design, structure and axial ligand perturbed magnetic dynamics

Xiao-Lei Li; Han Li; Di-Ming Chen; Chao Wang; Jianfeng Wu; Jinkui Tang; Wei Shi; Peng Cheng

doi:10.1039/c5dt03931b

Planar Dy3 + Dy3 clusters: design, structure and axial ligand perturbed magnetic dynamics

Dalton Trans. 2015 Dec 21;44(47):20316-20. doi: 10.1039/c5dt03931b. Epub 2015 Nov 9.

Authors

Xiao-Lei Li¹, Han Li, Di-Ming Chen, Chao Wang, Jianfeng Wu, Jinkui Tang, Wei Shi, Peng Cheng

Affiliation

¹ Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), and Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China.

PMID: 26549377
DOI: 10.1039/c5dt03931b

Abstract

Two unique Dy6 complexes with fascinating Dy3 + Dy3 structures were assembled, showing single-molecule magnetic behavior with high energy barriers of 116 and 181 K for Dy6-NO3 and Dy6-SCN.

Publication types

Research Support, Non-U.S. Gov't