PPAR-pan activation induces hepatic oxidative stress and lipidomic remodelling

Free Radic Biol Med. 2016 Jun:95:357-68. doi: 10.1016/j.freeradbiomed.2015.11.033. Epub 2015 Nov 30.

Abstract

The peroxisome proliferator-activated receptors (PPARs) are ligand activated nuclear receptors that regulate cellular homoeostasis and metabolism. PPARs control the expression of genes involved in fatty-acid and lipid metabolism. Despite evidence showing beneficial effects of their activation in the treatment of metabolic diseases, particularly dyslipidaemias and type 2 diabetes, PPAR agonists have also been associated with a variety of side effects and adverse pathological changes. Agonists have been developed that simultaneously activate the three PPAR receptors (PPARα, γ and δ) in the hope that the beneficial effects can be harnessed while avoiding some of the negative side effects. In this study, the hepatic effects of a discontinued PPAR-pan agonist (a triple agonist of PPAR-α, -γ, and -δ), was investigated after dietary treatment of male Sprague-Dawley (SD) rats. The agonist induced liver enlargement in conjunction with metabolomic and lipidomic remodelling. Increased concentrations of several metabolites related to processes of oxidation, such as oxo-methionine, methyl-cytosine and adenosyl-methionine indicated increased stress and immune status. These changes are reflected in lipidomic changes, and increased energy demands as determined by free fatty acid (decreased 18:3 n-3, 20:5 n-3 and increased ratios of n-6/n-3 fatty acids) triacylglycerol, phospholipid (decreased and increased bulk changes respectively) and eicosanoid content (increases in PGB2 and 15-deoxy PGJ2). We conclude that the investigated PPAR agonist, GW625019, induces liver enlargement, accompanied by lipidomic remodelling, oxidative stress and increases in several pro-inflammatory eicosanoids. This suggests that such pathways should be monitored in the drug development process and also outline how PPAR agonists induce liver proliferation.

Keywords: Eicosanoids; Lipidomics; Metabolomics; Peroxisome proliferator-activated receptors; β-Oxidation.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, N.I.H., Extramural

MeSH terms

  • Animals
  • Diabetes Mellitus, Type 2 / drug therapy
  • Diabetes Mellitus, Type 2 / pathology
  • Fatty Acids, Nonesterified / metabolism
  • Lipid Metabolism / genetics
  • Lipids / biosynthesis
  • Lipids / genetics
  • Liver / drug effects*
  • Liver / metabolism
  • Liver / pathology
  • Oxidative Stress / genetics*
  • PPAR alpha / agonists
  • PPAR alpha / genetics*
  • PPAR gamma / agonists
  • PPAR gamma / genetics*
  • PPAR-beta / agonists
  • PPAR-beta / genetics*
  • Rats
  • Rats, Sprague-Dawley

Substances

  • Fatty Acids, Nonesterified
  • Lipids
  • PPAR alpha
  • PPAR gamma
  • PPAR-beta