Abstract
A new class of anion transporter named 'perenosins' consisting of a pyrrole linked through an imine to either an indole, benzimidazole or indazole is reported. The indole containing members of the perenosin family function as effective transmembrane Cl(-)/NO3(-) antiporters and HCl cotransporters in a manner similar to the prodigiosenes. The compounds reduce the viability of MDA-MB-231 and MCF-7.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Anions / metabolism*
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Antineoplastic Agents, Phytogenic / chemical synthesis
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Antineoplastic Agents, Phytogenic / chemistry
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Antineoplastic Agents, Phytogenic / pharmacology*
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Antiporters / chemical synthesis
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Antiporters / chemistry
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Antiporters / pharmacology*
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Cell Line, Tumor
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Cell Proliferation / drug effects
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Cell Survival / drug effects
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Crystallography, X-Ray
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Dose-Response Relationship, Drug
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Drug Screening Assays, Antitumor
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Humans
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Imines / chemistry*
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Indoles / chemistry
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Indoles / pharmacology*
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Ion Transport / drug effects
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MCF-7 Cells
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Models, Molecular
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Molecular Structure
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Pyrroles / chemical synthesis
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Pyrroles / chemistry
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Pyrroles / pharmacology*
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Structure-Activity Relationship
Substances
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Anions
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Antineoplastic Agents, Phytogenic
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Antiporters
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Imines
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Indoles
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Pyrroles