Rpn1 provides adjacent receptor sites for substrate binding and deubiquitination by the proteasome

Science. 2016 Feb 19;351(6275):10.1126/science.aad9421 aad9421. doi: 10.1126/science.aad9421.

Abstract

Hundreds of pathways for degradation converge at ubiquitin recognition by a proteasome. Here, we found that the five known proteasomal ubiquitin receptors in yeast are collectively nonessential for ubiquitin recognition and identified a sixth receptor, Rpn1. A site ( T1: ) in the Rpn1 toroid recognized ubiquitin and ubiquitin-like ( UBL: ) domains of substrate shuttling factors. T1 structures with monoubiquitin or lysine 48 diubiquitin show three neighboring outer helices engaging two ubiquitins. T1 contributes a distinct substrate-binding pathway with preference for lysine 48-linked chains. Proximal to T1 within the Rpn1 toroid is a second UBL-binding site ( T2: ) that assists in ubiquitin chain disassembly, by binding the UBL of deubiquitinating enzyme Ubp6. Thus, a two-site recognition domain intrinsic to the proteasome uses distinct ubiquitin-fold ligands to assemble substrates, shuttling factors, and a deubiquitinating enzyme.

MeSH terms

  • DNA-Binding Proteins / metabolism
  • Endopeptidases / metabolism
  • Metabolic Networks and Pathways
  • Models, Molecular
  • Mutation
  • Proteasome Endopeptidase Complex / chemistry
  • Proteasome Endopeptidase Complex / genetics
  • Proteasome Endopeptidase Complex / metabolism*
  • Saccharomyces cerevisiae / metabolism*
  • Saccharomyces cerevisiae Proteins / chemistry*
  • Saccharomyces cerevisiae Proteins / genetics
  • Saccharomyces cerevisiae Proteins / metabolism*
  • Ubiquitin-Specific Proteases / metabolism
  • Ubiquitination

Substances

  • DNA-Binding Proteins
  • RAD23 protein, S cerevisiae
  • RPN1 protein, S cerevisiae
  • Saccharomyces cerevisiae Proteins
  • Endopeptidases
  • Ubiquitin-Specific Proteases
  • Proteasome Endopeptidase Complex
  • UBP6 protein, S cerevisiae