Manipulating three-dimensional gel network entanglement by thin film shearing

Chem Commun (Camb). 2016 Mar 25;52(24):4513-6. doi: 10.1039/c6cc00171h.

Abstract

Vortex fluidic mediated shearing of supramolecular gels in thin films leads to complete disruption of fluorous bis-urea derived gels. Hydrocarbon analogues however, are only partially disrupted, which emphasizes the resistance of non-fluorous bis-urea gelators towards shear. The gel structures have been studied by combining the thin film shearing with small angle neutron scattering. This technique represents a novel approach to study the effects of external stimuli on self-assembled supramolecular gel networks.

Publication types

  • Research Support, Non-U.S. Gov't