Nanocrystalline SSZ-39 zeolite as an efficient catalyst for the methanol-to-olefin (MTO) process

Nuria Martín; Zhibin Li; Joaquín Martínez-Triguero; Jihong Yu; Manuel Moliner; Avelino Corma

doi:10.1039/c5cc09719c

Nanocrystalline SSZ-39 zeolite as an efficient catalyst for the methanol-to-olefin (MTO) process

Chem Commun (Camb). 2016 Apr 26;52(36):6072-5. doi: 10.1039/c5cc09719c.

Authors

Nuria Martín¹, Zhibin Li², Joaquín Martínez-Triguero¹, Jihong Yu³, Manuel Moliner¹, Avelino Corma¹

Affiliations

¹ Instituto de Tecnología Química (UPV-CSIC), Universidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas, Valencia, 46022, Spain. [email protected] [email protected].
² Instituto de Tecnología Química (UPV-CSIC), Universidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas, Valencia, 46022, Spain. [email protected] [email protected] and School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China.
³ State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China.

PMID: 26947336
DOI: 10.1039/c5cc09719c

Abstract

The synthesis of nanosized SSZ-39 zeolite has been achieved using a high silica FAU zeolite as the Si and Al source and tetraethylphosphonium (TEP) cations as OSDAs. The obtained SSZ-39 material shows a remarkably high catalyst lifetime compared to conventional SSZ-13 and SSZ-39 materials.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alkenes / chemistry*
Catalysis
Methanol / chemistry*
Nanoparticles / chemistry*
Nanoparticles / ultrastructure
Silicon Dioxide / chemistry
Surface Properties
Zeolites / chemistry*

Substances

Alkenes
Zeolites
Silicon Dioxide
Methanol