Liquid chromatography-mass spectroscopy as a tool in the rapid diagnosis of biliary atresia: a pilot study

J Pediatr Surg. 2016 Jun;51(6):923-6. doi: 10.1016/j.jpedsurg.2016.02.053. Epub 2016 Mar 3.

Abstract

Introduction: Biliary atresia (BA) is a neonatal obstructive cholangiopathy requiring rapid intervention to prevent end-stage liver failure and death. Low bile acid levels in stool, detectable with high-performance liquid chromatography-mass spectroscopy, may reflect extrahepatic biliary obstruction in cholestasis.

Hypothesis: Stool bile acid content can differentiate BA from non-BA forms of cholestasis.

Methods: Stool samples from four healthy and nine cholestatic patients were collected following internal review board approval. Bile acids were extracted and separated on a 4000-Q-Trap HPLC-MS system.

Results: Total bile acid content was highest in samples from healthy relative to cholestatic patients: 3354.01 ± 2102.56, 1476.27 ± 1361.07, and 34.29 ± 10.30 μM/mg of stool in healthy, total parenteral nutrition-associated cholestasis, and BA samples, respectively. Mean cholic acid and chenodeoxycholic acid concentrations in healthy samples (2017.5 ± 1413.6 and 876.83 ± 660.60 μM/mg) were higher than in TPN cholestatic samples (93.99±131.55 and 232.34 ± 293.41 μM/mg). The most dramatic reduction in cholic acid and chenodeoxycholic acid was observed in BA samples (0.65 ± 0.47 and 1.22 ± 0.80 μM/mg).

Conclusion: Bile acid content in stool is reduced in cholestatic patients relative to healthy patients with the most dramatic reduction observed in BA-patients.

Keywords: Bile acids; Biliary atresia; HPLC.

Publication types

  • Clinical Trial

MeSH terms

  • Bile Acids and Salts / metabolism*
  • Biliary Atresia / complications
  • Biliary Atresia / diagnosis*
  • Biliary Atresia / metabolism
  • Biomarkers / metabolism
  • Case-Control Studies
  • Cholestasis / diagnosis
  • Cholestasis / etiology*
  • Cholestasis / metabolism
  • Chromatography, High Pressure Liquid*
  • Feces / chemistry
  • Female
  • Humans
  • Infant
  • Infant, Newborn
  • Male
  • Mass Spectrometry*
  • Pilot Projects
  • Prospective Studies

Substances

  • Bile Acids and Salts
  • Biomarkers