Determination of albendazole sulfoxide in human plasma by using liquid chromatography-tandem mass spectrometry

J Chromatogr B Analyt Technol Biomed Life Sci. 2016 Jun 1:1022:1-5. doi: 10.1016/j.jchromb.2016.03.024. Epub 2016 Mar 21.

Abstract

A rapid, simple and sensitive method was developed and validated using liquid chromatography-tandem mass spectrometry (LC-MS/MS) for determination of albendazole sulfoxide (ABZOX) in human plasma. The plasma samples were extracted by protein precipitation using albendazole sulfoxide-d3 as internal standard (IS). The chromatographic separation was performed on Waters Xbridge C18Column (100×4.6mm, 3.5μm) with a mobile phase consisting of ammonia solution, water and methanol at a flow rate of 0.70mL/min. ABZOX was detected and identified by mass spectrometry with electrospray ionization (ESI) in positive ion and multiple-reaction monitoring (MRM) mode. The method was linear in the range of 3-1500ng/mL for ABZOX. This method was successfully applied to the bioequivalence study in human plasma samples.

Keywords: Albendazole; Albendazole sulfoxide; Albendazole sulfoxide-d3; Human plasma; LC–MS/MS.

MeSH terms

  • Albendazole / analogs & derivatives*
  • Albendazole / blood
  • Albendazole / chemistry
  • Albendazole / pharmacokinetics
  • Chromatography, Liquid / methods*
  • Humans
  • Linear Models
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Tandem Mass Spectrometry / methods*

Substances

  • Albendazole
  • albendazole sulfoxide