Neutron Scattering from Polymers: Five Decades of Developing Possibilities

Annu Rev Chem Biomol Eng. 2016 Jun 7:7:1-28. doi: 10.1146/annurev-chembioeng-080615-034429.

Abstract

The first three decades of my research career closely map the development of neutron scattering techniques for the study of molecular behavior. At the same time, the theoretical understanding of organization and motion of polymer molecules, especially in the bulk state, was developing rapidly and providing many predictions crying out for experimental verification. Neutron scattering is an ideal technique for providing the necessary evidence. This autobiographical essay describes the applications by my research group and other collaborators of increasingly sophisticated neutron scattering techniques to observe and understand molecular behavior in polymeric materials. It has been a stimulating and rewarding journey.

Keywords: Autobiography; neutron scattering; polymer blends; polymer interfaces; polymer molecular dynamics; spinodal decomposition.

Publication types

  • Review

MeSH terms

  • Microscopy, Atomic Force
  • Molecular Weight
  • Neutron Diffraction*
  • Phase Transition
  • Polymers / chemistry*
  • Scattering, Small Angle

Substances

  • Polymers