A Bioorthogonal Approach for the Preparation of a Titanium-Binding Insulin-like Growth-Factor-1 Derivative by Using Tyrosinase

Angew Chem Int Ed Engl. 2016 Sep 12;55(38):11447-51. doi: 10.1002/anie.201603155. Epub 2016 Jul 6.

Abstract

The generation of metal surfaces with biological properties, such as cell-growth-enhancing and differentiation-inducing abilities, could be potentially exciting for the development of functional materials for use in humans, including artificial dental implants and joint replacements. However, currently the immobilization of proteins on the surfaces of the metals are limited. In this study, we have used a mussel-inspired bioorthogonal approach to design a 3,4-hydroxyphenalyalanine-containing recombinant insulin-like growth-factor-1 using a combination of recombinant DNA technology and tyrosinase treatment for the surface modification of titanium. The modified growth factor prepared in this study exhibited strong binding affinity to titanium, and significantly enhanced the growth of NIH3T3 cells on the surface of titanium.

Keywords: bioorthogonal chemistry; cell growth; growth factors; titanium; tyrosinase.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Cell Proliferation / drug effects
  • Chromatography, High Pressure Liquid
  • Immobilized Proteins / analysis
  • Immobilized Proteins / chemistry
  • Immobilized Proteins / pharmacology
  • Insulin-Like Growth Factor I / chemistry*
  • Insulin-Like Growth Factor I / genetics
  • Insulin-Like Growth Factor I / metabolism
  • Mice
  • Monophenol Monooxygenase / metabolism*
  • NIH 3T3 Cells
  • Quartz Crystal Microbalance Techniques
  • Recombinant Proteins / biosynthesis
  • Recombinant Proteins / chemistry
  • Recombinant Proteins / genetics
  • Surface Properties
  • Tandem Mass Spectrometry
  • Titanium / chemistry*
  • Titanium / metabolism

Substances

  • Immobilized Proteins
  • Recombinant Proteins
  • Insulin-Like Growth Factor I
  • Titanium
  • Monophenol Monooxygenase