OH-Initiated Oxidation of m-Xylene on Black Carbon Aging

Environ Sci Technol. 2016 Aug 16;50(16):8605-12. doi: 10.1021/acs.est.6b01272. Epub 2016 Aug 3.

Abstract

Laboratory experiments are conducted to investigate aging of size-classified black carbon (BC) particles from OH-initiated oxidation of m-xylene. The variations in the particle size, mass, effective density, morphology, optical properties, hygroscopicity, and activation as cloud condensation nuclei (CCN) are simultaneously measured by a suite of aerosol instruments, when BC particles are exposed to the oxidation products of the OH-m-xylene reactions. The BC aging is governed by the coating thickness (Δrve), which is correlated to the reaction time and initial concentrations of m-xylene and NOx. For an initial diameter of 100 nm and Δrve = 44 nm, the particle size and mass increase by a factor of 1.5 and 10.4, respectively, and the effective density increases from 0.43 to 1.45 g cm(-3) due to organic coating and collapsing of the BC core. The BC particles are fully converted from a highly fractal to nearly spherical morphology for Δrve = 30 nm. The scattering, absorption, and single scattering albedo of BC particles are enhanced accordingly with organic coating. The critical supersaturation for CCN activation is reduced to 0.1% with Δrve = 44 nm. The results imply that the oxidation of m-xylene exhibits larger impacts in modifying the BC particle properties than those for the OH-initiated oxidation of isoprene and toluene.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aerosols*
  • Carbon / chemistry*
  • Oxidation-Reduction
  • Particle Size
  • Soot / chemistry*
  • Xylenes / chemistry*

Substances

  • Aerosols
  • Soot
  • Xylenes
  • Carbon