Multiantigenic peptide-polymer conjugates as therapeutic vaccines against cervical cancer

Bioorg Med Chem. 2016 Sep 15;24(18):4372-4380. doi: 10.1016/j.bmc.2016.07.036. Epub 2016 Jul 18.

Abstract

Immunotherapy is one of the most promising strategies for the treatment of cancer. Human papillomavirus (HPV) is responsible for virtually all cases of cervical cancer. The main purpose of a therapeutic HPV vaccine is to stimulate CD8(+) cytotoxic T lymphocytes (CTLs) that can eradicate HPV infected cells. HPV oncoproteins E6 and E7 are continuously expressed and are essential for maintaining the growth of HPV-associated tumor cells. We designed polymer-based multi-antigenic formulations/constructs that were comprised of the E6 and E7 peptide epitopes. We developed an N-terminus-based epitope conjugation to conjugate two unprotected peptides to poly tert-butyl acrylate. This method allowed for the incorporation of the two antigens into a polymeric dendrimer in a strictly equimolar ratio. The most effective formulations eliminated tumors in up to 50% of treated mice. Tumor recurrence was not observed up to 3months post initial challenge.

Keywords: Cervical cancer; Human papillomavirus; Multiantigenic; Peptide-based subunit vaccine; Polymer–peptide conjugate; Self-adjuvanting; Therapeutic cancer vaccine.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Antigens / chemistry*
  • Chromatography, High Pressure Liquid
  • Epitopes / chemistry
  • Epitopes / immunology
  • Female
  • Mice
  • Mice, Inbred C57BL
  • Papillomavirus Vaccines / chemistry
  • Papillomavirus Vaccines / immunology
  • Papillomavirus Vaccines / therapeutic use*
  • Peptides / chemistry*
  • Polymers / chemistry*
  • Spectrometry, Mass, Electrospray Ionization
  • Uterine Cervical Neoplasms / prevention & control*

Substances

  • Antigens
  • Epitopes
  • Papillomavirus Vaccines
  • Peptides
  • Polymers