Occurrence of polybrominated diphenyl ethers in indoor air and dust in Hangzhou, China: Level, role of electric appliances, and human exposure

This study investigated the occurrence of 8 polybrominated diphenyl ether (PBDE) congeners from homes (n = 20), offices (n = 20), air conditioners (n = 6), and computers (n = 6). High detection frequencies for most of the congeners were observed, indicating continued widespread use of Penta-, Octa- and Deca-BDE mixtures. The median concentrations of ∑PBDEs were 119 and 194 pg m^-3 for home air and office air, respectively. Regarding dust, the median concentrations of ∑PBDEs were 239 and 437 ng g^-1 for home and office dust, respectively. The ratios of the median concentrations of BDE-209 to ∑PBDEs were approximately 0.95 and 0.87 for home dust and office dust, respectively. The median concentrations of ∑PBDEs were 359 ng g^-1 and 350 ng g^-1 for dust on air conditioner filters and the back cabinet of the computer, respectively. The ratios of the median concentrations of BDE-209 to ∑PBDEs were approximately 0.58 and 0.46 for air conditioner and computer samples. Running air conditioners contributed to ΣPBDEs in office air through direct and indirect pathways. The daily intake of PBDEs was estimated to be 2630 pg (kg bw)^-1 day^-1 for toddlers in homes and 319 pg (kg bw)^-1 day^-1 for adults in homes and offices.