Ferulic acid esters of glucosylglucose from Allium macrostemon Bunge

J Asian Nat Prod Res. 2017 Mar;19(3):215-221. doi: 10.1080/10286020.2016.1213722. Epub 2016 Sep 2.

Abstract

Three new ferulic acid esters of glucosylglucose, 1-O-(E)-feruloyl-β-d-glucopyranosyl (1-2)-[β- d-glucopyranosyl (1-6)]-β-d-glucopyranose (allimacronoid A, 1), 1-O-(E)-feruloyl-{β-d-glucopyranosyl (1-4)-[β-d-glucopyranosyl (1-2)]}-[β- d-glucopyranosyl (1-6)]-β-d-glucopyranose (allimacronoid B, 2), and 1-O-(E)-feruloyl-{β-d-glucopyranosyl (1-6)-[β-d-glucopyranosyl (1-2)]}-[β- d-glucopyranosyl (1-6)]-β-d-glucopyranose (allimacronoid C, 3) were isolated together with tuberonoid A (4), from the leaves of Allium macrostemon Bunge. The chemical structures were elucidated based on the analyses of the spectroscopic and chemical data.

Keywords: Allium macrostemon; Amaryllidaceae; ester; ferulic acid; glucosylglucose.

MeSH terms

  • Allium / chemistry*
  • Coumaric Acids / chemistry
  • Coumaric Acids / isolation & purification*
  • Esters
  • Molecular Structure
  • Nuclear Magnetic Resonance, Biomolecular
  • Plant Leaves / chemistry
  • Saponins / chemistry
  • Saponins / isolation & purification*

Substances

  • Coumaric Acids
  • Esters
  • Saponins
  • allimacronoid A
  • allimacronoid B
  • allimacronoid C
  • tuberonoid A
  • ferulic acid