Characteristics of cadmium remobilization in tributary sediments in Three Gorges Reservoir using chemical sequential extraction and DGT technology

The Three Gorges Reservoir (TGR) is the largest reservoir in China. Cadmium (Cd) is a primary pollutant in the TGR, and its speciation and bioavailability have attracted extensive attention since TGR submergence. In this study, Chelex-100 DGT (diffusive gradient in thin films) and the sequential extraction method were used to investigate the bioavailable Cd in sediments obtained from a typical tributary (Meixi) and mainstream (Yangtze) in the TGR. The total Cd concentrations in sediments of the four stations were also determined. In comparison to the concentrations of labile Cd measured by DGT (C_DGT-Cd) in four profiles, CJ and MX-upstream/downstream were at potential risk for Cd release from surface sediments using the apparent diffusion flux across the interface numerical model. The order of C_DGT-Cd in surface sediments was as follows: CJ > MX-downstream > MX-upstream > MX-midstream. Additionally, a positive correlation was demonstrated between C_DGT-Cd and Cd in the exchangeable fraction (F1) in the surface sediments, indicating that Cd in the exchangeable fraction was readily captured by DGT. A negative correlation was observed between C_DGT-Cd and C_DGT-Fe, C_DGT-Mn in the sediment-water-interface (SWI), suggesting that Fe/Mn oxides did not control the release of labile-Cd from sediments. Furthermore, a positive correlation existed between the C_DGT-Cd in the surface sediments and Cd in the oxidizable fraction (F3), illustrating that Cd sorbed or bound with organic matter or sulfide was labile and released into the water phase from the surface sediments. A dark area was found in the AgI gel, which further demonstrated that Cd simultaneously was released with sulfide in this area.