A Water-Soluble Cationic Zinc Lysine Precursor for Coating ZnO on Biomaterial Surfaces

Inorg Chem. 2016 Oct 17;55(20):10094-10097. doi: 10.1021/acs.inorgchem.6b01663. Epub 2016 Sep 30.

Abstract

A novel water-soluble cationic zinc lysine coordination compound, [Zn[(C6H14N2O2)]2Cl]Cl·2H2O (1), has been designed and synthesized and its crystal structure determined. The aqueous solution of this coordination compound is not only transparent and stable at room temperature but it is also nearly neutral (pH ∼ 7). It is worth noting that zinc oxide (ZnO) forms in situ upon dilution of a solution of the compound. The bioactivity of ZnO has been confirmed using an Alarma Blue assay. These unique properties allow the coordination compound to gently grow ZnO coating with excellent antibacterial benefits onto biomaterial surfaces in a facile and safe manner.

MeSH terms

  • Animals
  • Anti-Bacterial Agents / chemistry
  • Anti-Bacterial Agents / pharmacology
  • Biocompatible Materials / chemistry*
  • Coordination Complexes / chemistry*
  • Coordination Complexes / pharmacology
  • Humans
  • Lysine / chemistry*
  • Lysine / pharmacology
  • Skin / chemistry
  • Solubility
  • Staphylococcus aureus / drug effects
  • Swine
  • Water / chemistry
  • Zinc Oxide / chemistry*
  • Zinc Oxide / pharmacology

Substances

  • Anti-Bacterial Agents
  • Biocompatible Materials
  • Coordination Complexes
  • Water
  • Lysine
  • Zinc Oxide