A Deep Hydrophobic Binding Cavity is the Main Interaction for Different Y2 R Antagonists

ChemMedChem. 2017 Jan 5;12(1):75-85. doi: 10.1002/cmdc.201600433. Epub 2016 Nov 30.

Abstract

The neuropeptide Y2 receptor (Y2 R) is involved in various pathophysiological processes such as epilepsy, mood disorders, angiogenesis, and tumor growth. Therefore, the Y2 R is an interesting target for drug development. A detailed understanding of the binding pocket could facilitate the development of highly selective antagonists to study the role of Y2 R in vitro and in vivo. In this study, several residues crucial to the interaction of BIIE0246 and SF-11 derivatives with Y2 R were investigated by signal transduction assays. Using the experimental results as constraints, the antagonists were docked into a comparative structural model of the Y2 R. Despite differences in size and structure, all three antagonists display a similar binding site, including a deep hydrophobic cavity formed by transmembrane helices (TM) 4, 5, and 6, as well as a hydrophobic patch at the top of TM2 and 7. Additionally, we suggest that the antagonists block Q3.32 , a position that has been shown to be crucial for binding of the amidated C terminus of NPY and thus for receptor activation.

Keywords: G protein-coupled receptors; antagonists; binding models; neuropeptide Y.

MeSH terms

  • Animals
  • Arginine / analogs & derivatives*
  • Arginine / chemistry
  • Arginine / pharmacology
  • Benzazepines / chemistry*
  • Benzazepines / pharmacology*
  • Binding Sites
  • COS Cells
  • Cells, Cultured
  • Chlorocebus aethiops
  • Dose-Response Relationship, Drug
  • HEK293 Cells
  • Humans
  • Hydrophobic and Hydrophilic Interactions*
  • Molecular Docking Simulation
  • Molecular Structure
  • Receptors, Neuropeptide Y / antagonists & inhibitors*
  • Receptors, Neuropeptide Y / chemistry*
  • Structure-Activity Relationship

Substances

  • Benzazepines
  • Receptors, Neuropeptide Y
  • neuropeptide Y2 receptor
  • Arginine
  • BIIE 0246